Viscosity

Definition

Viscosity describes the internal resistance of a fluid to flow or deformation. It is one of the most important fluid properties to consider when designing a mixer. There are two common measures of viscosity: dynamic viscosity (µ) and kinematic viscosity (ν). They are related as follows:


Kinematic viscosity formula: ν = µ / ρ ν – kinematic viscosity (cSt)
µ – dynamic viscosity (cP)
ρ – density (g/cm3)

Dynamic viscosity is the most relevant for mixing, as it describes the resistance of a fluid to flow under shear stress, whereas kinematic viscosity describes its resistance to flow under gravity.

Newtonian Fluids

In a Newtonian fluid, dynamic viscosity is the ratio of shear stress to velocity gradient. It remains constant whatever the shear stress and over time, as shown below:


Shear stress formula: τ = µ du/dy τ – shear stress
µ – dynamic viscosity
du/dy – velocity gradient

Most fluids can be treated as Newtonian, and these are the fluids found in most mixing applications.

Non-Newtonian Fluids

Other fluids show non-Newtonian behaviour: their viscosity is not constant but varies with another parameter. The main types are:

  • Pseudoplastic (shear-thinning) fluids are the most common non-Newtonian fluids. Their viscosity decreases as the applied shear rate increases.
  • Thixotropic fluids behave like pseudoplastic fluids, but their viscosity also decreases over time under shear.
  • Dilatant and rheopectic fluids are the opposite of pseudoplastic and thixotropic fluids: their viscosity increases with shear rate and with shearing time respectively.
  • Viscoelastic fluids combine viscous and elastic properties under stress: to some extent they behave like an elastic solid and tend to return to their original shape after deformation.
  • Bingham plastics need a minimum shear stress (yield stress) before they start to flow.

Common non-Newtonian fluids include water-based paints, polymer solutions and many food and personal care products, such as toothpaste and tomato ketchup.

Measuring Viscosity

Viscosity is measured with a viscometer or rheometer. The most common types are described below.

Falling-ball viscometer

Falling-Ball Viscometer

A falling-ball viscometer consists of a small ball and a fixed glass tube filled with the fluid to be tested. The ball is dropped through the fluid and the time it takes to travel between two marks is measured. The dynamic viscosity is then calculated with Stokes’ law, using the densities of the fluid and of the ball.

Viscosity Cups

A viscosity cup is a cup with a precisely sized orifice in its base. The cup is filled with the liquid and the time it takes to drain through the orifice is recorded. The kinematic viscosity is then calculated with the conversion formulas or tables supplied by the manufacturer.

Viscosity cups are widely used in the paint and coatings industries.


Rotational viscometer Viscosity cups

Rotational Viscometer

The rotational viscometer is a more sophisticated instrument. It works on the Searle principle: the torque needed to rotate a spindle in the fluid at a given speed is proportional to the viscosity of the fluid.

The spindle speed can usually be adjusted, which varies the shear applied to the fluid. Rotational viscometers can therefore measure the viscosity profile of non-Newtonian fluids, whose viscosity changes with the shear rate.

Viscosity of Common Liquids

Typical absolute viscosity of common liquids in centipoise (cP), by product category. Values are for guidance only and may vary with temperature, concentration and supplier.

LiquidSpecific gravity at 16 °CAbsolute viscosity (cP)Temperature (°C)Viscosity type
●  Dairy Products
Butter30,000Room temp.
Butter cream, sour550Room temp.
Butter, deodorised4550N
Butterfat2065N
Cheese, soft30,000Room temp.
Cocoa butter0.925060N
Condensed milk40–8040–50N
Condensed milk, 75% solids1.32,16020T
Cottage cheese30,00018T
Cream cheese100,000Room temp.
Cream, 30% fat1.01416N
Cream, 45% fat0.994816N
Cream, 50% fat0.9811216N
Cream, 50% fat5532N
Cream, clotted20,000Room temp.
Cream, double120Room temp.
Cream, single50Room temp.
Cream, sour15,200Room temp.
Milk1.02–1.05218N
Milk whey, 48% sugar800–1,50040T
Milk, condensed6,000Room temp.
Milk, evaporated6,100Room temp.
Processed cheese30,00018T
Whey800–1,500Room temp.
Whole egg1504.5T
Yoghurt3,000–8,000Room temp.
●  Fish & Animal Oils
Bone oil0.924854N
Cod oil0.933238N
Lard0.966238N
Lard oil0.91–0.9340–4738N
Sperm oil0.882438N
Whale oil0.9325–3938N
●  Food Products
Apple sauce1.150080T
Baby food1,40093T
Batter29,50030T
Beer18Room temp.
Beet sauce1,95076T
Biscuit cream premix29,20018T
Brewer’s yeast36818T
Broth mix43018T
Carob bean sauce1,50030T
Chocolate28049T
Chocolate syrup2,250Room temp.
Citrus fruit pulp1.2760020T
Coffee liquor 30–4010–10020T
Corn syrup15,000Room temp.
Custard1.61,50085–90T
Edible oil0.96520N
Fruit juice1.0455–7518N
Gelatine1,200Room temp.
Gelatine, 37% solids1,19043T
Glucose1.34,300–8,60025–30T
Gravy slurry1.011080T
Honey1,800–3,000Room temp.
Icing10,000Room temp.
Jam8,500Room temp.
Jam garnish8,44016T
Malt extract1.43,00060T
Malt extract 809,50018T
Maple syrup150–300Room temp.
Mayonnaise5,000–20,000Room temp.
Mincemeat100,00030T
Molasses5,000–10,000Room temp.
Mousse mix1,2005T
Orange juice concentrate30 °Brix63020N
Pancake batter2,200Room temp.
Peanut butter150,000–250,000Room temp.
Pectin30038N
Rice pudding10,000100T
Salad cream1,300–2,60018T
Sorbitol1.2920020N
Soya bean slurry5,000–10,00050–90T
Spaghetti sauce1,000Room temp.
Starch solution 25%300Room temp.
Sugar syrup, sucrose1,210Room temp.
Tomato juice180Room temp.
Tomato ketchup1,00030T
Tomato ketchup1,000Room temp.
Tomato paste 3019518T
Tomato purée50,000Room temp.
Tomato sauce2,600Room temp.
Vinegar12–1520N
Yeast slurry2018T
●  Fuel & Lubricating Oils
Fuel oil no. 412Room temp.
Hydraulic oil30–120Room temp.
Lubricating oil60–200Room temp.
Machine oil, heavy600Room temp.
Machine oil, light150Room temp.
Motor oil SAE 1050Room temp.
Motor oil SAE 20125Room temp.
Motor oil SAE 30200Room temp.
Motor oil SAE 40320Room temp.
Motor oil SAE 50540Room temp.
Motor oil SAE 601,000Room temp.
Motor oil SAE 701,600Room temp.
●  Glycol Products
Diethylene glycol1.123221N
Ethylene glycol1.121821N
Ethylene glycol16Room temp.
Glycol20Room temp.
Propylene glycol1.045221N
Triethylene glycol1.124021N
●  Industrial Products
Acetate glue1,200–1,40020T
Alkyd resins500–3,000Room temp.
Antifreeze15Room temp.
Benzine5Room temp.
Caulking compound5,000,000–10,000,000Room temp.
Caustic soda 50%45Room temp.
Cleaning emulsions1,500Room temp.
Cresol crystals1018T
Diesel14Room temp.
Dipropylene glycol107Room temp.
Epoxy resin5,000–10,000Room temp.
Glue, gun grade5,000–50,000Room temp.
Glue, pourable3,000–5,000Room temp.
Glycerine 100%1.26 at 20 °C64820N
Isopropyl alcohol2Room temp.
Isopropyl alcohol1.111.985N
Kerosene10Room temp.
Lacquer, 25% solids3,00018T
Methyl ethyl ketone4Room temp.
NaOH 20%1.22118N
NaOH 30%1.33118N
NaOH 40%1.432018N
Paraffin10Room temp.
Petrol8Room temp.
Plastisol2.528,00018T
Polyester1.1 at 30 °C3,00030T
Polyester resin3,000Room temp.
Polyglycerine caprinate6,000–7,000Room temp.
Polyisobutylene1.09 at 85 °C12,50085T
Polymer solution20,000Room temp.T
Polyol, non-pigmented500–5,000Room temp.
Polypropylene240,00050T
Potassium hydroxide67Room temp.
Printing ink550–2,20038T
Printing ink, liquid550–2,200Room temp.
Putty100,000,000Room temp.
PVA resin65,000Room temp.
Resin solution88024T
Resin solution7,100Room temp.
Resin, pourable880–975Room temp.
Sulphonic acid1.0412530T
Titanium dioxide5,000Room temp.
Toluene6Room temp.
Triacetate dope48,000–60,00040T
●  Paints & Varnishes
Lacquer, 25% pigments3,000Room temp.
Lacquer, water-based900Room temp.
Latex neoprene5,000Room temp.T
Latex paint750Room temp.T
Paint, water-based2,400Room temp.
Varnish320Room temp.
●  Pharmaceuticals
Blood10Room temp.
Detergents1,47070T
Glycerine1,000–2,000Room temp.
Hand cream8,000Room temp.
Hand lotion5,000Room temp.
Latex emulsion1.020024T
Liquid soap85Room temp.
Paraffin emulsion1.23,00018T
Petroleum jelly64,000Room temp.
Shampoo3,000–5,000Room temp.
Soap solution1.03 at 60 °C8260T
Soap, Arylan1.0 at 40 °C63060T
Toothpaste70,000–100,00018T
Wax0.950093T
●  Vegetable Oils
Castor oil0.9658027N
Chinawood oil (tung oil)0.9430021N
Coconut oil0.935524N
Corn oil0.922857N
Cottonseed oil0.886224N
Linseed oil30–70Room temp.
Linseed oil, raw0.93–0.942938N
Oleic acid40Room temp.
Olive oil0.914038N
Palm oil0.924338N
Peanut oil0.923838N
Peanut oil100Room temp.
Sesame oil94Room temp.
Soya bean oil0.936024N
Turpentine0.86216N
Vegetable oil40Room temp.

N Newtonian    T Thixotropic (non-Newtonian)    1 cP = 1 mPa·s    Source: Euromixers

Viscosity Cup Conversion Table

Efflux time in seconds for each viscosity cup, against kinematic viscosity in centistokes (cSt). Read across from your cup and flow time to find the viscosity. Scroll sideways to see all values.

Cup type \ cSt12347.5101520253040506070809010012515017520022525027530032535037540050060070080090010001250
Shell cups
‘Ultra Low’ cup536884
Shell cup #11721.526354657
Shell cup #218.32230.4394756
Shell cup #2.519253035.646.657
Shell cup #318.62228.635424855
Shell cup #3.517.52024.629.23438.44347.859.4
Shell cup #4182124273037455260
Shell cup #516202428323640444852566064
Shell cup #617.51920.522.5242531.537.5445056.56378
Zahn cups
Zahn cup #130.53235384245526068
Zahn cup #218192022.5252830343843536372
Zahn cup #31719.52224.527303235.53841434548.55870
Zahn cup #4171819.52122.52426283032384551546570
Zahn cup #51718.5202122.527313540454960
Ford / ISO / DIN / AFNOR cups
Ford cup #3323740435363738393103113120130
Ford cup #42022252835404855627076829098103
ISO cup #4263339465360
DIN cup #420222426283035404650566171
AFNOR cup #420222426283035404650566171
Norcross cups
Norcross cup #1313640537087
Norcross cup #21923283445556776
Norcross cup #31720253035404550556879
Norcross cup #41822273236404448535761656885
Norcross cup #5202226313641455062

Values in seconds. Source: Euromixers.

Effect on Mixing

Viscosity is one of the most important factors to consider when designing a mixer for a given application.

The higher the viscosity, the more energy is needed for mixing, which means larger impellers and more powerful motors. For highly viscous products, a close-clearance impeller such as a gate or helical ribbon impeller may be needed to mix the whole tank volume properly.

Laminar and Turbulent Mixing

Low-viscosity mixing almost always takes place in turbulent flow. Mixing is then governed by inertial forces rather than molecular diffusion, and is achieved by the many eddies created by the impeller.

Impellers such as hydrofoils and pitched-blade turbines are used for low-viscosity mixing because they give high pumping capacity and create strong turbulence in the vessel.

High-viscosity mixing, by contrast, takes place mainly in laminar flow: viscous forces dominate and suppress turbulence, and molecular diffusion is the main mixing mechanism. To promote diffusion, laminar mixing aims to “cut and fold” the fluid, increasing the interfacial area between the different fluids.

Anchor and helical ribbon impellers are used here, because their large contact area with the fluid enhances this “cut and fold” action throughout the tank.

The chart below shows the suitable viscosity range for each type of standard impeller.

Table of Impeller Types and Their Appropriate Operating Viscosities
Chart of impeller types by operating viscosity range

Mixing Non-Newtonian Fluids

Mixing non-Newtonian fluids properly can be difficult. If you have a non-Newtonian application and need help choosing a mixer, contact us: our application engineers will be happy to help.

Static Mixers

Viscosity affects in-line static mixers in the same way as agitated tanks. At low viscosity, mixing is driven by turbulent eddies; at high viscosity, it always relies on molecular diffusion and on the same “cut and fold” principle as the agitated tanks described above.

Different mixing elements are used for low- and high-viscosity fluids, following the same principles as tank impellers. The higher the viscosity, the larger and more complex the elements inside the pipe must be to mix evenly across the whole pipe diameter. This increases the pressure drop and therefore the pump power required: as with agitated tanks, high-viscosity fluids need more power to mix.

Static mixer elementStatic mixer elements